|
Customer
Testimonials and Field Tests/Demonstrations
|
The case study
outlined below includes ONLY the brief summary of its individual
test background and result; please feel free to contact your local
dealer if you want
to know more about how TK Series can help your unique plastic
processing. |
| Case#
024: How TK additives would affect the MFI or MFR
characteristic of plastic resins?
|
|
Customer: |
Philippines, Brazil & Indonesia
|
| Product: |
special purpose plastic resins in
pellets or granules
|
| Resin
Type: |
virgin LDPE and virgin PP
|
| Process: |
extrusion or injection
|
|
Filler Type |
none |
|
Customer concerns: |
Different customers plan to include TK
additives as one of the key ingredients when making their special purpose
compounding resins. They request to know how MFI (MFR) value will
be affected by TK. |
| MFI
Test Record (LDPE) |
sample quantity: 100 gms
Test Performed at: Kayeness, Inc.
Test Date: 03/03/2008
MI Model: 4002
Test Method: ASTM D1238 (Procedure A)
|
Temp: 190 deg. C
Load: 2.16 kgs
Melt Time: 360 seconds
Method A Time: 180 seconds
MFI (MFR) measurement unit: g/10 minutes
|
| |
without
TK |
0.1%
TK |
0.2%
TK |
| MFR,
X1 |
1.923 |
2.187 |
2.067 |
| MFR,
X2 |
1.873 |
2.180 |
2.063 |
| MFR,
Average |
1.898 |
2.184 |
2.065 |
| MFR
Range, |X1 -
X2| |
0.050 |
0.007 |
0.004 |
| MFR
Increase, % |
- |
15% |
9% |
| Range
Comparison |
7.1 |
1.0 |
0.6 |
|
MFI
Test Record
(PP)
|
sample quantity: 100 gms
Test Performed at: Kayeness, Inc.
Test Date: 03/04/2008
MI Model: 4002
Test Method: ASTM D1238 (Procedure A)
|
Temp: 175 deg. C
Load: 2.16 kgs
Melt Time: 360 seconds
Method A Time: 180 seconds
MFI (MFR) measurement unit: g/10 minutes
|
| |
without
TK |
0.1%
TK |
0.2%
TK |
| MFR,
X1 |
6.260 |
7.063 |
6.603 |
| MFR,
X2 |
6.367 |
7.023 |
6.633 |
| MFR,
Average |
6.314 |
7.043 |
6.618 |
| MFR
Range, |X1 -
X2| |
0.107 |
0.040 |
0.030 |
| MFR
Increase, % |
- |
12% |
5% |
| Range
Comparison |
2.7 |
1.0 |
0.8 |
|
| Discussion |
- MFI with standard TK dosage will increase 15% for LDPE and
12% for PP (see Discussion #3)
- MFI range can be reduced after TK treatment; the range ratio
is about 7:1 for LDPE and 3:1 for PP (see Discussion #4)
- MFI is an assessment of average molecular mass and is an inverse measure of the melt viscosity. In other words, the higher an MFI, the more polymer flows under test conditions.
TK helps the processing of lower melt index, tougher, stronger resins. Lower
MFI resins treated with TK can be used at a lower gauge with equivalent strength, saving
power and raw material expenses.
- Besides the MFI value increase; the other important
advantage of TK upon MFI is that TK would significantly reduce
the RANGE of MFI of plastic resins. The reason is probably
that the resin (especially for recycled resin) may suffer from
either crosslinking or polymer chain scission during
reprocessing, both altering the molecular-weight distribution
which in turn will result in an inconsistent MFI value from
batch to batch of the resin production, and in the worst case,
even within the same batch of the resin. Eventually this
inconsistent MFI (i.e. larger range or higher deviation of MFI
value) will potentially cause processing problems for
subsequent users and an adverse effect in the physical
properties of its finished products. TK additives, with its
unique chemical and physical properties; is able to mitigate
the weakness due to inconsistent MFI value and subsequently
avoid the unfavorable processing errors.
- More MFI tests should be performed to verify the possible
over-lubrication effect when using higher TK dosages (i.e.
0.2% TK in above tests).
- Additional MFI tests will be tested for recycled resins and
resins with calpet.
|
Return
to Main Testimonial Page
|